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亚星游戏登录:Cu2(OH)PO4, a Near-Infrared-Activated Photocatalyst†

Authors

  • 亚星游戏登录:Gang Wang,

    1. State Key Lab of Crystal Materials, Shandong University, Jinan 250100 (China) http://www.icm.sdu.edu.cn/index.php
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  • 亚星游戏登录:Prof. Dr. Baibiao Huang,

    Corresponding author
    1. State Key Lab of Crystal Materials, Shandong University, Jinan 250100 (China) http://www.icm.sdu.edu.cn/index.php
    • State Key Lab of Crystal Materials, Shandong University, Jinan 250100 (China) http://www.icm.sdu.edu.cn/index.php
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  • 亚星游戏登录:Xiangchao Ma,

    1. School of physics, Shandong University (China)
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  • 亚星游戏登录:Zeyan Wang,

    1. State Key Lab of Crystal Materials, Shandong University, Jinan 250100 (China) http://www.icm.sdu.edu.cn/index.php
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  • 亚星游戏登录:Xiaoyan Qin,

    1. State Key Lab of Crystal Materials, Shandong University, Jinan 250100 (China) http://www.icm.sdu.edu.cn/index.php
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  • 亚星游戏登录:Prof. Xiaoyang Zhang,

    1. State Key Lab of Crystal Materials, Shandong University, Jinan 250100 (China) http://www.icm.sdu.edu.cn/index.php
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  • 亚星游戏登录:Prof. Dr. Ying Dai,

    1. School of physics, Shandong University (China)
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  • 亚星游戏登录:Prof. Dr. Myung-Hwan Whangbo

    1. Department of Chemistry, North Carolina State University, Raleigh, NC 276955-8204 (USA)
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  • †

    This work was financially supported by the National Basic Research Program of China (973 Program, No.2013CB632401) and the National Natural Science Foundation of China (Nos. 20973102, 51021062 and 51002091).

Abstract

original image

Crystal power! Libethenite, Cu2(OH)PO4 (see 4–5 μm×1.5 μm image), absorbs strongly in the near-infrared (NIR) region and is an effective photocatalyst for the decomposition of 2,4-dichlorophenol in aqueous solution under NIR irradiation. This NIR activation of the photocatalyst is due to a facile transfer of photogenerated electrons from the trigonal bipyramidal CuII sites to the adjacent octahedral CuII sites.

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亚星游戏登录:Article Information

DOI

10.1002/anie.201301306

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Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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Keywords

  • copper;
  • nanocrystals;
  • near-infrared light;
  • photocatalysts;
  • photochemistry

Publication History

  • Issue online:
  • Version of record online:
  • Manuscript Received:

Funded by

  • National Basic Research Program of China. Grant Number: 2013CB632401
  • National Natural Science Foundation of China. Grant Numbers: 20973102, 51021062, 51002091

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